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Adsorption of polyampholytes on charged surfaces

机译:聚电解质在带电表面上的吸附

摘要

We have studied the adsorption of neutral polyampholytes on model chargedsurfaces that have been characterized by contact angle and streaming currentmeasurements. The loop size distributions of adsorbed polymer chains have beenobtained using atomic force microscopy (AFM) and compared to recent theoreticalpredictions. We find a qualitative agreement with theory; the higher thesurface charge, the smaller the number of monomers in the adsorbed layer, inagreement with theory. We propose an original scenario for the adsorption ofpolyampholytes on surfaces covered with both neutral long-chain and chargedshort-chain thiols.
机译:我们已经研究了中性多两性电解质在模型带电表面的吸附,该表面已通过接触角和流动电流测量进行了表征。已使用原子力显微镜(AFM)获得了吸附的聚合物链的环尺寸分布,并与最近的理论预测进行了比较。我们发现与理论有质的一致性。与理论相符,表面电荷越高,吸附层中的单体数量越少。我们提出了一种在中性长链和带电短链硫醇均覆盖的表面上吸附两性电解质的原始方案。

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